Theory ofВ three-electrone bond inВ the four works with brief comments

Volodymyr Bezverkhniy

The three-electron theory of communication accepted for granted the existence of threeelectron bonds (one axiom), everything else is derived logically. And if think… reflect the existence of three-electron bond directly from the theory of resonance (resonance structures do not exist, in reality there is something average between them – and now think that should really be the basis of this, some real structure?.. of course the three-electron bond!!!).

Theory ofВ three-electrone bond inВ the four works with brief comments

Volodymyr Dmytrovich Bezverkhniy

Translator Vitaliy Volodymyrovich Bezverkhniy

© Volodymyr Dmytrovich Bezverkhniy, 2017

© Vitaliy Volodymyrovich Bezverkhniy, translation, 2017

ISBNВ 978-5-4483-0206-0

Created with Ridero smart publishing system

IВ express my deep gratitude toВ my son, Bezverkhniy Vitaliy Volodymyrovich, for participation inВ the development ofВ the theory (some parts as aВ co-author), and for his invaluable contribution toВ the English translation.

1.В BezverkhniyВ V. D. Structure ofВ the benzene molecule onВ the

basis ofВ the three-electron bond.

http://vixra.org/pdf/1606.0152v1.pdf

2.В BezverkhniyВ V. D. Experimental confirmation ofВ the existence ofВ the three-electron bond and theoretical basis ot its existence.

http://vixra.org/pdf/1606.0151v1.pdf

3.В BezverkhniyВ V. D. AВ short analysis ofВ chemical bonds.

http://vixra.org/pdf/1606.0149v2.pdf

4.В BezverkhniyВ V.В D., BezverkhniyВ V.В V.В Supplement toВ the theoretical justification ofВ existence ofВ the three-electron bond.

http://vixra.org/pdf/1606.0150v1.pdf

5.В Bezverkhniy Volodymyr Dmytrovych (viXra):

http://vixra.org/author/bezverkhniy_volodymyr_dmytrovych

Note 1. Three-electrone bond it is an existing particle (object)

Three-electrone bond it is an existing bond, not aВ mathematical or physical model.

And if the three-electron bond exist, then:

1) We can represent the one true formule of benzene (p. 3 – 5 Structure of the benzene molecule on the basis of the three-electron bond. http://vixra.org/pdf/1606.0152v1.pdf).

One of the drawbacks of the resonance theory is that resonance structures do not exist in reality, and their objectification is a mistake. And assuming the existence of three-electron bond, we can represent the real formula of benzene, aromatic compounds, carboxylate anion, ozone, oxygen, etc. (p. 19—29 Structure of the benzene molecule on the basis of the three-electron bond. http://vixra.org/pdf/1606.0152v1.pdf).

2) We can simply and clearly explain the increase inВ the multiplicity ofВ benzene from 1.5В toВ 1.67. byВ MO method calculations give aВ value ofВ 1.67, but Pauling from resonant structures, which is logical (2В and 4В ofВ the electron) gaveВ 1.5.

If the multiplicity is greater than 1.5В (eg 1.67), since the communication multiplicity inВ classical chemistry correlates with the amount ofВ the bonding electrons (even if it is average) like:

2 electrons multiplicityВ 1;

4В electrons multiplicityВ 2;

6В electrons multiplicityВ 3;

thene inВ benzene at aВ multiplicity ofВ 1.67В inВ six (6) aromatic bonds as it further appears 1В electron:

1.67 – 0.17 = 1.5

6В * 0.17В =В 1.02

At the three-electron bond in benzene and interaction through a simple explanation of the cycle – the cycle just a little compressed.

3)В We can check experimentally: if the three-electron bond and interaction through the cycle are real, then it logically follows the bending real chemical bond density inВ benzene into benzene.

It is important that the maximum density of the chemical bond will be shifted to the center of the benzene cycle link, which is what we are seeing in the atomic force microscopy images (AFM) pentacene (p. 1—2 Experimental confirmation of the existence of the three-electron bond and theoretical basis of its existence. http://vixra.org/pdf/1606.0151v1.pdf).

4)В Experimental predicted effects: anti-aromatic system (core system) s